After a thorough analysis for both relational database management system solutions, it is clear that we cannot recommend PostgreSQL for large enterprise applications. PostgreSQL will be a better fit if you need to purchase a product with a free license. Furthermore, if you need a DBMS with more advanced features and also need to handle large databases with complex queueing, then again PostgreSQL will be suitable. However, MySQL is the best choice if you are looking for a safer, fast, reliable, and scalable option with a shorter learning curve. After all, you are the one who knows more details about your project. So the choice is up to you, whilst keeping in mind what we discussed here.